Scott Summers-X-Men
Danny Saunders-The Chosen (I am CONVINCED this is canon and they just didn't say it cause it's set in the 40s)
Illya Kuryakin-The Man from UNCLE (More of a TV Show than a movie, but eh, plus they're making a reboot of it next year! )
Steve Rogers-Avengers (OK, this is weird but there is SOMETHING about the way he talks and holds himself, the way he never quite looks anyone in the eye, his fighty-ness and how all of his social skills are either "stilted" (compared with the other characters) or explicitly scripted, just SOMETHING that screams autistic to me)
Natasha Romanoff-Avengers
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Er ist der große Mauerbrecher, der eine stumme Arbeit hat.
He is the great wall breaker, who has a silent work.
-"Ihr vielen unbestürmten Städte/All you undisturbed cities" by Rainer Maria Rilke