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Now, Vic Sage aka The Question might be an aspie--especially the Justice League Unlimited version. In JLU Vic finds it very hard to make friends or fit in, but he's extremely smart and obsessed with conspiracies...
I totally agree with this assessment of The Question. You can tell he starting to learn how to interact with people at the start of Question Authority too. Id have to say Wally West Flash is an Aspie too. Contrary to his goofy nature he is a very smart man, and After overcoming The Wall after the death of the previous Flash, His Uncle Barry Allen, He actually refuses to become the flash for a couple of weeks cause he couldn't handle the pressure of taking up such a role. (i think so many continuities) as well as this he is particularly somewhat blind to normal societal manners and over-exaggerates his flirting as well as only catching onto subtle social cues after some nudging.
In regards to anime however I would Have to say that Crona from soul Eater would be the most aspie after L and Near
In terms of Marvel though, Tony I would say is as close to being aspie without being it. He has social skills and he can read body language just fine.
However there are hundreds of Heroes with Marvel and DC to explore on such a topic.