I use to work for a small business owned by very cheap people who paid their employees peanuts and claimed they couldn't afford to give pay raises. Now I work for a fortune 500 company and am paid pretty well. I prefer bigger companies because if they are making billions, you know they can afford to pay for you and more positions will be available within the company.
On the other hand, if you are working a low skilled position, bigger companies could be worse because you are more likely to be seen as an expendable, unskilled, nameless, necessary evil as opposed to smaller companies that may actually know who you are.
At the end of the day, it's always going to be about what your position entails that dictates how your work experience will be.
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"The less I know about other people's affairs, the happier I am. I'm not interested in caring about people. I once worked with a guy for three years and never learned his name. The best friend I ever had. We still never talk sometimes."